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Electrical-field induced structural change and charge transfer of lanthanide-salophen based complexes assembled on Carbon Nanotube Field Effect Transistor devices

Gurvan Magadur, Fatima Bouanis, Jean-Sébastien Lauret, Evgeny Norman, Régis Guillot, Vincent Huc, Costel-Sorin Cojocaru, Talal Mallah, Chem Commun 48, 9071-9073 (2012)

The application of a negative gate voltage on a carbon nanotube field effect transistor decorated by a binuclear Tb(III) complex leads to the generation of a negatively charged mononuclear one, presenting an electron density transfer to the nanotube and ambipolar behaviour.

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